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Dr. Hongqiang Liu, Mohamed El-Salfiti and Prof. Dr. Mark Lautens Expeditious Synthesis of Tetrasubstituted Helical Alkenes by a Cascade of Palladium-Catalyzed C[BOND]H Activations Angewandte Chemie International Edition 51

Version of Record online: 24 AUG 2012 | DOI: 10.1002/anie.201204226

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Twisted molecules: A modular approach for the synthesis of tetrasubstituted helical alkenes by a palladium-catalyzed norbornene-mediated domino reaction is presented. This intermolecular domino process allows the formation of three C[BOND]C bonds in one operation through a C[BOND]H activation/carbopalladation/C[BOND]H activation sequence.

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