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Qiankun Li, Prof. Dr. Chunling Fu and Prof. Dr. Shengming Ma Catalytic Asymmetric Allenylation of Malonates with the Generation of Central Chirality Angewandte Chemie International Edition 51

Article first published online: 10 OCT 2012 | DOI: 10.1002/anie.201204346

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Water plays an important role in a palladium-catalyzed allenylation of diethyl malonate with 2,3-allenyl acetates to yield centrally chiral allenyl malonates bearing synthetically useful functional groups (see scheme). The products were formed with 92–96 % ee in the presence of a bulky, electron-rich biphenyl ligand at room temperature.

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