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Koji Naoda, Hirotaka Mori, Dr. Naoki Aratani, Byung Sun Lee, Prof. Dr. Dongho Kim and Prof. Dr. Atsuhiro Osuka Hexaphyrin Fused to Two Anthracenes Angewandte Chemie International Edition 51

Version of Record online: 2 AUG 2012 | DOI: 10.1002/anie.201204446

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Gold standard: A bis(AuIII) complex containing the title compound was prepared and characterized (see scheme; DDQ=2,3-dichloro-5,6-dicyano-1,4-benzoquinone, Tf=trifluoromethanesulfonyl). Owing to the effective conjugative network over the flat and elongated rectangular molecular frame, this complex displays a remarkably red-shifted and sharp Q-band-like band at 1467 nm, multiple reversible redox potentials, and a large TPA cross-section value.

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