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Xu Jing, Dr. Cheng He, Dapeng Dong, Linlin Yang and Prof. Chunying Duan Homochiral Crystallization of Metal–Organic Silver Frameworks: Asymmetric [3+2] Cycloaddition of an Azomethine Ylide Angewandte Chemie International Edition 51

Article first published online: 7 SEP 2012 | DOI: 10.1002/anie.201204530

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Enantiomeric silver-based MOFs were obtained through a homochiral crystallization of cinchonine and cinchonidine enantiomers as chiral adducts with silver. These MOFs exhibited excellent catalytic activity for asymmetric [3+2] cycloaddition (see scheme), giving products with high enantioselectivity.

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