Dr. Saeed Kamali, Dr. Hongxin Wang, Dr. Devrani Mitra, Dr. Hideaki Ogata, Prof. Wolfgang Lubitz, Brian C. Manor, Prof. Thomas B. Rauchfuss, Dr. Deborah Byrne, Dr. Violaine Bonnefoy, Prof. Francis E. Jenney Jr., Prof. Michael W. W. Adams, Dr. Yoshitaka Yoda, Dr. Ercan Alp, Dr. Jiyong Zhao and Prof. Stephen P. Cramer Observation of the FeCN and FeCO Vibrations in the Active Site of [NiFe] Hydrogenase by Nuclear Resonance Vibrational Spectroscopy Angewandte Chemie International Edition 52
Version of Record online: 8 NOV 2012 | DOI: 10.1002/anie.201204616
Nuclear inelastic scattering of 57Fe labeled [NiFe] hydrogenase is shown to give information on different states of the enzyme. It was thus possible to detect and assign FeCO and FeCN bending and stretching vibrations of the active site outside the spectral range of the FeS cluster normal modes.
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