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Dr. Yuzhong Wang, Dr. Yaoming Xie, Mariham Y. Abraham, Robert J. Gilliard Jr., Dr. Pingrong Wei, Dr. Charles F. Campana, Prof. Dr. Henry F. Schaefer III, Prof. Dr. Paul von R. Schleyer and Prof. Dr. Gregory H. Robinson NHC-Stabilized Triorganozincates: Syntheses, Structures, and Transformation to Abnormal Carbene–Zinc Complexes Angewandte Chemie International Edition 51

Article first published online: 7 SEP 2012 | DOI: 10.1002/anie.201204712

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Anion is superior: NHC-based triorganozincates, from mononuclear to trinuclear, have been synthesized. The NHC-based triorganozincate chain (see scheme; left) was transformed into an abnormal carbene (aNHC)-complexed zinc ring (right) by reaction with MeOTf, closing the aNHC-Group 12 complexes gap.

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