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Dr. Shigeki Yamamoto and Dr. Petr Bouř Detection of Molecular Chirality by Induced Resonance Raman Optical Activity in Europium Complexes Angewandte Chemie International Edition 51

Version of Record online: 28 SEP 2012 | DOI: 10.1002/anie.201204765

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Beef up the signal: Induced resonance Raman optical activity (IRROA) in the presence of a europium complex enabled the detection of molecular chirality (see picture) with a 104-fold increase in sensitivity relative to that observed with conventional nonresonant vibrational ROA. The method can thus be used as a sensitive tool for the determination of the absolute configuration and enantiomeric excess of organic and biologically relevant compounds.

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