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Baoqiang Wan and Prof. Dr. Shengming Ma Enantioselective Decarboxylative Amination: Synthesis of Axially Chiral Allenyl Amines Angewandte Chemie International Edition 52

Version of Record online: 7 SEP 2012 | DOI: 10.1002/anie.201204796

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Getting axed: Synthesis of the title amines, bearing functionality (R1 and R2), involves the enantioselective palladium-catalyzed decarboxylation of allenyl N-tosylcarbamates. The reaction proceeds smoothly using both the chiral ligands (S)- and (R)-DTBM-Segphos (1) to afford the allenyl amines in good yields and with high enantioseletivities.

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