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Prof. Dr. Shifa Zhu, Renxiao Liang, Prof. Dr. Huanfeng Jiang and Dr. Wanqing Wu An Efficient Route to Polysubstituted Tetrahydronaphthols: Silver-Catalyzed [4+2] Cyclization of 2-Alkylbenzaldehydes and Alkenes Angewandte Chemie International Edition 51

Version of Record online: 26 SEP 2012 | DOI: 10.1002/anie.201204798

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Silver bullet: A methodology for stereoselective synthesis of polysubstituted tetrahydronaphthols catalyzed by [Ag+]/NPO has been developed. The reactions proceeded through an unprecedented [4+2] cyclization of 2-(2-formylphenyl)ethanone and an alkene, in both inter- and intramolecular fashion. NPO=pyridine N-oxide.

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