Dr. V. Guillerm, F. Ragon, Dr. M. Dan-Hardi, Dr. T. Devic, Dr. M. Vishnuvarthan, Dr. B. Campo, Dr. A. Vimont, Dr. G. Clet, Prof. Q. Yang, Prof. G. Maurin, Prof. G. Férey, Dr. A. Vittadini, Dr. S. Gross and Dr. Christian Serre A Series of Isoreticular, Highly Stable, Porous Zirconium Oxide Based Metal–Organic Frameworks Angewandte Chemie International Edition 51
Article first published online: 9 AUG 2012 | DOI: 10.1002/anie.201204806
Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one-dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts.
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