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Dr. Valeriu Mereacre Differentiation of Highly Anisotropic TbIII and DyIII with 57Fe Mössbauer Spectroscopy Angewandte Chemie International Edition 51

Version of Record online: 3 SEP 2012 | DOI: 10.1002/anie.201204838

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Using 57Fe Mössbauer spectroscopy, three examples of coordination compounds with different topologies containing FeIII and LnIII ions (DyIII and TbIII; see diagram; insets: clusters cores) were analyzed. In the same crystal field environment, Dy and Tb ions show different degrees of anisotropy, which can be qualitatively detected using an indirect method.

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