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Yi Chang, Huachao Chen, Zhikuan Zhou, Yue Zhang, Christian Schütt, Prof. Rainer Herges and Prof. Zhen Shen A 20π-Electron Heteroporphyrin Containing a Thienopyrrole Unit Angewandte Chemie International Edition 51

Version of Record online: 9 NOV 2012 | DOI: 10.1002/anie.201204954

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Easy as π: A stable nonaromatic heteroporphyrin bearing a thienopyrrole moiety has been prepared. The nonaromatic nature of this compound is clearly evident based on UV/Vis absorption, 1H NMR spectroscopy, and theoretical calculations. Single-crystal X-ray analysis demonstrates that the molecule adopts a planar conformation with clear alternation in the C[BOND]C bond lengths around the periphery of the macrocycle.

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