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Prof. Xuefeng Wang, Prof. Dr. Lester Andrews, Knut Willmann, Dipl.-Chem. Felix Brosi and Dr. Sebastian Riedel Investigation of Gold Fluorides and Noble Gas Complexes by Matrix-Isolation Spectroscopy and Quantum-Chemical Calculations Angewandte Chemie International Edition 51

Version of Record online: 23 SEP 2012 | DOI: 10.1002/anie.201205072

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Noble with a difference: Matrix-isolation experiments and quantum-chemical calculations have led to the characterization of two new compounds, namely first open-shell binary gold fluoride, AuF2, and a NeAuF complex. Moreover, ArAuF, AuF3, Au2F6, and monomeric AuF5 have been produced and identified under cryogenic conditions in neon and argon matrices.

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