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Justus Hermannsdörfer, Martin Friedrich, Dr. Nobuyoshi Miyajima, Prof. Dr. Rodrigo Q. Albuquerque, Prof. Dr. Stephan Kümmel and Prof. Dr. Rhett Kempe Ni/Pd@MIL-101: Synergistic Catalysis with Cavity-Conform Ni/Pd Nanoparticles Angewandte Chemie International Edition 51

Version of Record online: 12 OCT 2012 | DOI: 10.1002/anie.201205078

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A perfect fit: Cavity-conform bimetallic Ni/Pd nanoparticles of different composition were generated in the metal–organic framework MIL-101. Experimental evidence and molecular dynamic simulations indicate the existence of mixed bimetallic particles. Pronounced synergistic effects have been observed in liquid-phase catalysis.

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