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Ch. G. Chandaluri and Prof. T. P. Radhakrishnan Amorphous-to-Crystalline Transformation with Fluorescence Enhancement and Switching of Molecular Nanoparticles Fixed in a Polymer Thin Film Angewandte Chemie International Edition 51

Article first published online: 17 OCT 2012 | DOI: 10.1002/anie.201205081

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Growth in a confined environment: A protocol for the amorphous-to-crystalline transformation (ACT) of nanoparticles has been developed, the critical step being the partial confinement of the particles by fixing in a polymer thin film and solvent vapor fuming. The ACT of a diaminodicyanoquinodimethane-based nanoparticle is accompanied by substantial fluorescence enhancement and switching of the emission color.

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