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Dr. Chu-Hung Wei, Dr. Subramaniyan Mannathan and Prof. Dr. Chien-Hong Cheng Regio- and Enantioselective Cobalt-Catalyzed Reductive [3+2] Cycloaddition Reaction of Alkynes with Cyclic Enones: A Route to Bicyclic Tertiary Alcohols Angewandte Chemie International Edition 51

Version of Record online: 13 SEP 2012 | DOI: 10.1002/anie.201205115

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Round and round: An unusual cobalt-catalyzed regio- and enantioselective reductive [3+2] cycloaddition of cyclic enones with alkynes affording bicyclic tertiary alcohols is described. A possible mechanism involving the formation of a cobaltacyclopentene intermediate is proposed.

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