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Dr. Venugopal Thottempudi, Dr. Farhad Forohor, Dr. Damon A. Parrish and Prof. Dr. Jean'ne M. Shreeve Tris(triazolo)benzene and Its Derivatives: High-Density Energetic Materials Angewandte Chemie International Edition 51

Article first published online: 3 SEP 2012 | DOI: 10.1002/anie.201205134

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High-performance explosives: Tris(triazolo)benzene was synthesized and converted to its trinitro and trichloro derivatives (see scheme; R=NO2, Cl). The heats of formation of this “high-nitrogen” compounds were calculated and combined with experimentally determined densities to determine detonation pressures and velocities. They exhibit high density, good thermal stability, high heats of formation, and moderate to good detonation properties.

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