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Tobias D. Blümke, Thomas Klatt, Prof. Dr. Konrad Koszinowski and Prof. Dr. Paul Knochel InCl3-Catalyzed Synthesis of 1,2-Dimetallic Compounds by Direct Insertion of Aluminum or Zinc Powder Angewandte Chemie International Edition 51

Version of Record online: 5 SEP 2012 | DOI: 10.1002/anie.201205169

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In-sertion of metal: Catalytic amounts of InCl3 allow the insertion of aluminum and zinc into aromatic 1,2-dibromides or 1,2-bromotriflates (see scheme). These 1,2-dimetallic species can undergo Cu or Pd-catalyzed acylations, allylations, or cross-couplings.

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