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Emanuele Maggio, Dr. Natalia Martsinovich and Prof. Alessandro Troisi Using Orbital Symmetry to Minimize Charge Recombination in Dye-Sensitized Solar Cells Angewandte Chemie International Edition 52

Article first published online: 28 NOV 2012 | DOI: 10.1002/anie.201205184

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Suitably designed symmetric dyes can be used in dye-sensitized solar cells to reduce the charge recombination rate by two to three orders of magnitude. If the electron coupling between the electrode and the dye is mediated by a conjugated linker, it is possible to design dyes for which the HOMO of the dye is not coupled to the semiconductor.

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