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Dr. Moritz F. Kuehnel, Prof. Dr. Dieter Lentz and Prof. Dr. Thomas Braun Synthesis of Fluorinated Building Blocks by Transition-Metal-Mediated Hydrodefluorination Reactions Angewandte Chemie International Edition 52

Article first published online: 25 JAN 2013 | DOI: 10.1002/anie.201205260

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Keen on fluorine: Metal-induced C[BOND]F bond activation is emerging as a promising tool to access partly fluorinated molecules (see scheme). Hydrodefluorination has been achieved in the coordination sphere of various transition-metal complexes and features a unique mechanistic diversity.

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