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Juan F. Araneda, Dr. Benedikt Neue and Prof. Warren E. Piers Enforced Planarity: A Strategy for Stable Boron-Containing π-Conjugated Materials Angewandte Chemie International Edition 51

Article first published online: 29 AUG 2012 | DOI: 10.1002/anie.201205265

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Catching a plane: A new strategy for stabilizing the B[BOND]C bonds in boron-containing π-conjugated materials has been demonstrated. Encasing the boron in a rigid, planarized environment (see scheme) has been shown by Yamaguchi and co-workers to give air- and moisture-stable organoboranes that bring the boron's p orbital into full conjugation with the organic π framework.

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