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Dr. Knut Kölbel, Dr. Christian H. Ihling and Prof. Dr. Andrea Sinz Analysis of Peptide Secondary Structures by Photoactivatable Amino Acid Analogues Angewandte Chemie International Edition 51

Article first published online: 26 OCT 2012 | DOI: 10.1002/anie.201205308

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Photochemical cross-linking was applied to trap intramolecular interactions in peptides. The incorporation of diazirine-labeled amino acid analogues in combination with high-resolution mass spectrometry made it possible to catch reverse-turn conformations within peptides, exactly map their self-interacting surfaces, and discriminate between stable and transient interactions.

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