Dr. Blanca Inés, Dr. David Palomas, Sigrid Holle, Sebastian Steinberg, Juan A. Nicasio and Dr. Manuel Alcarazo Metal-Free Hydrogenation of Electron-Poor Allenes and Alkenes Angewandte Chemie International Edition 51
The poorer, the better: A metal-free catalytic procedure for the reduction of electron-poor allenes and alkenes has been developed. The method employs a frustrated Lewis pair based catalyst. 1,4-Diazabicyclo[2.2.2]octane (DABCO)/B(C6F5)3 was shown to be the best combination in optimization studies.
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