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Jürgen Bauer, Prof. Dr. Holger Braunschweig, Alexander Damme and Dr. Krzysztof Radacki Reversible Insertion of Platinum into Coinage Group Metal–Halogen Bonds Angewandte Chemie International Edition 51

Article first published online: 7 SEP 2012 | DOI: 10.1002/anie.201205438

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M&Ms: The reversible insertion of a platinum complex into coinage group metal–halogen bonds results in a series of unsupported metal-only Lewis pairs with a Lewis basic platinum(0) fragment and cationic copper, silver, and gold Lewis acids (see scheme; M=Cu, Ag, Au; Cy=cyclohexyl). This is a convenient route to mixed d10–d10 complexes.

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