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Dr. Paulo N. Martinho, Brendan Gildea, Michelle M. Harris, Dr. Tibebe Lemma, Dr. Anil D. Naik, Dr. Helge Müller-Bunz, Prof. Tia E. Keyes, Prof. Dr. Yann Garcia and Dr. Grace G. Morgan Cooperative Spin Transition in a Mononuclear Manganese(III) Complex Angewandte Chemie International Edition 51

Article first published online: 5 NOV 2012 | DOI: 10.1002/anie.201205573

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Mind the gap: A complete, cooperative spin transition for a mononuclear MnIII complex is reported with an 8 K hysteresis window. Raman spectra collected at a single temperature in warming and cooling modes confirm the electronic bistability within the hysteresis loop. The source of the cooperativity is a disconnection in the hydrogen-bonded 1D chains that connect adjacent cations owing to an order–disorder transition in the PF6 counterion.

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