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Le Meng, Qigan Cheng, Chungsik Kim, Wen-Yang Gao, Lukasz Wojtas, Yu-Sheng Chen, Prof. Michael J. Zaworotko, Prof. X. Peter Zhang and Prof. Shengqian Ma Crystal Engineering of a Microporous, Catalytically Active fcu Topology MOF Using a Custom-Designed Metalloporphyrin Linker Angewandte Chemie International Edition 51

Article first published online: 5 SEP 2012 | DOI: 10.1002/anie.201205603

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A 12-connected fcu metal–organic framework (MOF), MMPF-3, has been prepared using a CoII metalloporphyrin. MMPF-3 is comprised of the same polyhedral supermolecular building blocks as the prototypal fcu-MOF, fcu-MOF-1, and its nanoscale cavities feature 18 catalytically active cobalt centers. The high density (ca. 5 cobalt sites/nm3) affords MMPF-3 superior performance in catalytic epoxidation of trans-stilbene compared to other MOFs.

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