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Tobias Hoppe, Stefan Schaub, Jonathan Becker, Dr. Christian Würtele and Prof. Dr. Siegfried Schindler Characterization of a Macrocyclic end-on Peroxido Copper Complex Angewandte Chemie International Edition 52

Version of Record online: 23 NOV 2012 | DOI: 10.1002/anie.201205663

Thumbnail image of graphical abstract

Thirty years on: The dinuclear copper peroxido complex [(tet b)CuO2Cu(tet b)]2+ has been structurally characterized (see picture: Cu yellow, O red, N pink; tet b=rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane). This complex is quite persistent in solution at room temperature and is the first example of a structurally characterized copper dioxygen adduct complex with a macrocyclic ligand based on earlier studies by Valentine et al.

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