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Appaso Mahadev Jadhav, Vinayak Vishnu Pagar and Prof. Dr. Rai-Shung Liu Development of a Povarov Reaction/Carbene Generation Sequence for Alkenyldiazocarbonyl Compounds Angewandte Chemie International Edition 51

Version of Record online: 18 OCT 2012 | DOI: 10.1002/anie.201205692

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Rings aplenty: A HOTf-catalyzed (Tf=trifluoromethanesulfonyl) Povarov reaction of alkenyldiazo species has been developed and delivers diazo-containing cycloadducts stereoselectively (see scheme). The resulting cycloadducts provide access to six- and seven-membered azacycles through the generation of metal carbenes as well as the functionalization of diazo group.

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