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Youngsoon Kim, Dr. Eui-seong Moon, Sunghwan Shin and Prof. Heon Kang Acidic Water Monolayer on Ruthenium(0001) Angewandte Chemie International Edition 51

Version of Record online: 8 NOV 2012 | DOI: 10.1002/anie.201205756

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Acidic water: The first monolayer of water on a Ru(0001) surface is anomalously acidic compared to bulk water, according to infrared and mass spectroscopic investigations of the water layer using ammonia as a probe for surface acidity. The observation suggests that acid–base chemistry may be quite different at the water–metal interfaces than in aqueous solution.

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