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Dr. Huibin Qiu, Giuseppe Russo, Dr. Paul A. Rupar, Dr. Laurent Chabanne, Prof. Mitchell A. Winnik and Prof. Ian Manners Tunable Supermicelle Architectures from the Hierarchical Self-Assembly of Amphiphilic Cylindrical B–A–B Triblock Co-Micelles Angewandte Chemie International Edition 51

Article first published online: 15 OCT 2012 | DOI: 10.1002/anie.201205764

Thumbnail image of graphical abstract

Crossing the block: Amphiphilic cylindrical B–A–B triblock co-micelles, micelle analogues of bolaamphiphiles, can be prepared by the crystallization-driven living self-assembly of diblock copolymers with core-forming polyferrocenylsilane blocks. These novel co-micelle building blocks form regular crossed or spherical supermicelles or elongated networks in polar media depending on the relative lengths of the A and B segments (see picture).

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