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Dr. Cristina Stefaniu, Dr. Ivan Vilotijevic, Dr. Mark Santer, Dr. Daniel Varón Silva, Prof. Dr. Gerald Brezesinski and Prof. Dr. Peter H. Seeberger Subgel Phase Structure in Monolayers of Glycosylphosphatidylinositol Glycolipids Angewandte Chemie International Edition 51

Version of Record online: 7 NOV 2012 | DOI: 10.1002/anie.201205825

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Heads and tails: GPI glycolipid monolayers on the air/liquid interface are characterized by the ordering of entire molecules, as observed by grazing-incidence X-ray diffraction. Strong hydrogen bonding interactions are responsible for ordering of the head groups to form supercells. These forces are likely to be the key to the interactions of GPI-anchored proteins and/or GPIs in cell membranes.

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