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Dr. Alan R. Burns, Jorge Solana González and Dr. Hon Wai Lam Enantioselective Copper(I)-Catalyzed Borylative Aldol Cyclizations of Enone Diones Angewandte Chemie International Edition 51

Version of Record online: 28 SEP 2012 | DOI: 10.1002/anie.201205899

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Piña colato? In the presence of a chiral CuI/bisphosphine complex and B2(pin)2, enone diones undergo diastereo- and enantioselective desymmetrization to deliver highly functionalized bicyclic products. The products can be used as substrates in additional transformations. pin=pinacolato, Cy=cyclohexyl.

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