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Dr. Marie-Emmanuelle Boulon, Giuseppe Cucinotta, Dr. Javier Luzon, Chiara Degl'Innocenti, Mauro Perfetti, Dr. Kevin Bernot, Dr. Guillaume Calvez, Prof. Dr. Andrea Caneschi and Prof. Dr. Roberta Sessoli Magnetic Anisotropy and Spin-Parity Effect Along the Series of Lanthanide Complexes with DOTA Angewandte Chemie International Edition 52

Version of Record online: 3 DEC 2012 | DOI: 10.1002/anie.201205938

Thumbnail image of graphical abstract

Spotting trends: Upon going from TbIII to YbIII centers in the complexes of the DOTA4− ligand, a reorientation of the easy axis of magnetization from perpendicular to parallel to the Ln[BOND]O bond of the apical water molecule is experimentally observed and theoretically predicted (see picture; SMM=single-molecule magnet). Only ions with an odd number of electrons show slow relaxation of the magnetization.

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