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Ji-Cheng Wu, Lu-Bing Gong, Dr. Yuanzhi Xia, Ren-Jie Song, Ye-Xiang Xie and Prof. Dr. Jin-Heng Li Nickel-Catalyzed Kumada Reaction of Tosylalkanes with Grignard Reagents to Produce Alkenes and Modified Arylketones Angewandte Chemie International Edition 51

Version of Record online: 3 SEP 2012 | DOI: 10.1002/anie.201205969

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Open a new door: The first example of alkene synthesis from alkyl electrophiles with Grignard reagents using the Kumada cross-coupling reaction strategy is reported. This method opens a new door for the Kumada cross-coupling reaction, allowing alkenes to be prepared from the reaction of tosylalkanes with Grignard reagents.

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