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John M. Clark, Dr. Shin-ichi Nishimura, Prof. Atsuo Yamada and Prof. M. Saiful Islam High-Voltage Pyrophosphate Cathode: Insights into Local Structure and Lithium-Diffusion Pathways Angewandte Chemie International Edition 51

Version of Record online: 14 NOV 2012 | DOI: 10.1002/anie.201205997

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Ion-transport paths: Combined modeling and neutron diffraction studies provide atomic-scale insights into Li2FeP2O7, a material proposed for a new lithium-battery cathode with reversible electrode operation at the highest voltage of all known Fe-based phosphates. The results indicate that Li+ ions are transported rapidly through a 2D network along the paths shown in green in the picture.

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