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Alexander Schoedel, Dr. Amy J. Cairns, Dr. Youssef Belmabkhout, Dr. Lukasz Wojtas, Mona Mohamed, Zhenjie Zhang, Prof. Davide M. Proserpio, Prof. Dr. Mohamed Eddaoudi and Prof. Dr. Michael J. Zaworotko The asc Trinodal Platform: Two-Step Assembly of Triangular, Tetrahedral, and Trigonal-Prismatic Molecular Building Blocks Angewandte Chemie International Edition 52

Version of Record online: 10 FEB 2013 | DOI: 10.1002/anie.201206042

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The self-assembly of triangular, tetrahedral, and trigonal-prismatic molecular building blocks affords the first example of a trinodal family of metal–organic materials. Four examples of isoreticular expanded and functionalized frameworks are detailed. Gas adsorption experiments validated the permanent porosity of the parent structure.

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