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Mette Stokkebro Schmøkel, Lasse Bjerg, Dr. Jacob Overgaard, Dr. Finn Krebs Larsen, Dr. Georg Kent Hellerup Madsen, Dr. Kunihisa Sugimoto, Prof. Dr. Masaki Takata and Prof. Dr. Bo Brummerstedt Iversen Pushing X-ray Electron Densities to the Limit: Thermoelectric CoSb3 Angewandte Chemie International Edition 52

Article first published online: 13 DEC 2012 | DOI: 10.1002/anie.201206065

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A big challenge: The experimental electron density of CoSb3 was determined based on short-wavelength single-crystal synchrotron data (10 K), thereby giving a view of covalently bonded Co and Sb atoms that carry only small negative and positive charges, respectively. This result contradicts the conventional view of the electrostatic properties of the structure used in thermoelectric studies.

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