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Dr. Esmeralda Caballero, Javier Fernández-Ariza, Prof. Vincent M. Lynch, Dr. Carlos Romero-Nieto, Dr. M. Salomé Rodríguez-Morgade, Prof. Jonathan L. Sessler, Prof. Dirk M. Guldi and Prof. Tomás Torres Cyclopentadienylruthenium π Complexes of Subphthalocyanines: A “Drop-Pin” Approach To Modifying the Electronic Features of Aromatic Macrocycles Angewandte Chemie International Edition 51

Version of Record online: 9 OCT 2012 | DOI: 10.1002/anie.201206111

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Facing facts: Coordination of Cp*Ru (Cp*=C5Me5) to the concave and convex π surfaces of subphthalocyanines constitutes a new approach to the functionalization of subazaporphyrins. While the convex face shows higher reactivity, coordination to the concave side produces a stronger diatropic influence on the Cp* ligand and a greater perturbation of the macrocyclic π-electronic features.

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