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Dr. Naoki Ishida, Yasuhiro Shimamoto and Prof. Dr. Masahiro Murakami Solar-Driven Incorporation of Carbon Dioxide into α-Amino Ketones Angewandte Chemie International Edition 51

Article first published online: 6 NOV 2012 | DOI: 10.1002/anie.201206166

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Power of the sun: Carbon dioxide was incorporated into α-amino ketones through a consecutive process consisting of a solar-energy-harvesting photocyclization reaction and a nucleophilic CO2 incorporation reaction. The single-flask operation produced amino-substituted cyclic carbonates, thereby presenting a simple model of the chemical utilization of solar energy for CO2 incorporation. R=sulfonyl group.

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