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Dr. Jinho Kim, Hyun Jin Kim and Prof. Sukbok Chang Synthesis of Aromatic Nitriles Using Nonmetallic Cyano-Group Sources Angewandte Chemie International Edition 51

Version of Record online: 6 NOV 2012 | DOI: 10.1002/anie.201206168

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Introducing CN: Recently, a range of nonmetallic organic cyano-group precursors (see scheme) have been developed as attractive alternatives to metal cyanides that have been frequently employed in the catalytic cyanation of aryl halides. This Minireview summarizes the development of organic cyano-group precursors and their application in the cyanation of aryl halides, boronates, boronic acids, arene carboxylic acids, and (hetero)arene C[BOND]H bonds.

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