E-mail

E-mail a Wiley Online Library Link

Dr. Masaru Enomoto, Dr. Akira Morita and Prof. Dr. Shigefumi Kuwahara Total Synthesis of the Tremorgenic Indole Diterpene Paspalinine Angewandte Chemie International Edition 51

Article first published online: 7 NOV 2012 | DOI: 10.1002/anie.201206299

Thumbnail image of graphical abstract

Succinct and stereoselective: A high-yielding two-step indole ring installation comprising the Stille cross-coupling and a PdII-mediated oxidative heterocyclization was exploited in a concise total synthesis of paspalinine. The trans-anti-trans CDE fused ring system of the heptacyclic natural product was established highly stereoselectively through hydroxy-directed cyclopropanation and allylic selenoxide rearrangement.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field

SEARCH