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Alexandra F. Bushell, Prof. Peter M. Budd, Dr. Martin P. Attfield, Dr. James T. A. Jones, Dr. Tom Hasell, Prof. Andrew I. Cooper, Dr. Paola Bernardo, Fabio Bazzarelli, Dr. Gabriele Clarizia and Dr. Johannes C. Jansen Nanoporous Organic Polymer/Cage Composite Membranes Angewandte Chemie International Edition 52

Version of Record online: 6 DEC 2012 | DOI: 10.1002/anie.201206339

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Organic–organic composite membranes are prepared by in situ crystallization of cage molecules in a polymer of intrinsic microporosity. This allows a direct one-step route to mixed-matrix membranes, starting with a homogeneous molecular solution. Extremely high gas permeabilities are achieved, even after ageing for more than a year, coupled with good selectivity for applications such as CO2 recovery.

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