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Dr. Ruijiao Dong, Prof. Bangshang Zhu, Prof. Yongfeng Zhou, Deyue Yan and Xinyuan Zhu “Breathing” Vesicles with Jellyfish-like On–Off Switchable Fluorescence Behavior Angewandte Chemie International Edition 51

Article first published online: 12 OCT 2012 | DOI: 10.1002/anie.201206362

Thumbnail image of graphical abstract

Controlled, deep breathing: Polymeric vesicles that exhibit reversible pH-induced “breathing” behavior accompanied by switchable fluorescence (see picture) were prepared through the aqueous self-assembly of an amphiphilic block copolymer. Mechanistic studies showed that this jellyfish-like breathing and light-emitting behavior originates from protonation- or deprotonation-induced changes in the conformation of the azobenzene chromophores.

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