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Prof. Dr. Timothy D. Lash, Aaron D. Lammer and Prof. Dr. Gregory M. Ferrence Two-Step Synthesis of Stable Dioxadicarbaporphyrins from Bis(3-indenyl)methane Angewandte Chemie International Edition 51

Version of Record online: 23 SEP 2012 | DOI: 10.1002/anie.201206385

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Porphyrin without N: Bilin analogues and related aromatic dicarbaporphyrinoids have been prepared from bis(3-indenyl)methane. Even though all four pyrrole rings from the porphyrin macrocycle have been replaced by two furan and two indene subunits, the system retains porphyrin-like UV/Vis spectra and highly diatropic characteristics.

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