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Dr. Mikhail Zibinsky and Prof. Valery V. Fokin Sulfonyl-1,2,3-Triazoles: Convenient Synthones for Heterocyclic Compounds Angewandte Chemie International Edition 52

Article first published online: 17 DEC 2012 | DOI: 10.1002/anie.201206388

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As easy as 1,2,3: Readily available and shelf-stable 1-sulfonyl-1,2,3-triazoles react with aldehydes and aldimines in the presence of RhII catalysts to produce 4-oxazolines and 1,2,5-trisubstituted imidazoles (see scheme).

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