E-mail a Wiley Online Library Link

Dragoş-Adrian Roşca, Dr. Dan A. Smith, Dr. David L. Hughes and Prof. Manfred Bochmann A Thermally Stable Gold(III) Hydride: Synthesis, Reactivity, and Reductive Condensation as a Route to Gold(II) Complexes Angewandte Chemie International Edition 51

Version of Record online: 20 SEP 2012 | DOI: 10.1002/anie.201206468

Thumbnail image of graphical abstract

Going for gold: The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air-stable AuII product, [(C N C)*2Au2], with a short nonbridged gold–gold bond.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field