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Hua Zhang, Renyi Shi, Anxing Ding, Lijun Lu, Borui Chen and Prof. Aiwen Lei Transition-Metal-Free Alkoxycarbonylation of Aryl Halides Angewandte Chemie International Edition 51

Version of Record online: 5 NOV 2012 | DOI: 10.1002/anie.201206518

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Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.

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