Hua Zhang, Renyi Shi, Anxing Ding, Lijun Lu, Borui Chen and Prof. Aiwen Lei Transition-Metal-Free Alkoxycarbonylation of Aryl Halides Angewandte Chemie International Edition 51
Transitions: The title reaction has been developed for the synthesis of a variety of tert-butyl benzoates by employing 1,10-phenanthroline as an additive. Various functional groups were tolerated and heteroaryl iodides were also suitable substrates. Preliminary mechanism studies were conducted and indicate the participation of radical intermediates.
Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf