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Andreu Ruiz de la Oliva, Dr. Victor Sans, Dr. Haralampos N. Miras, Dr. Jun Yan, Hongying Zang, Dr. Craig J. Richmond, Dr. De-Liang Long and Prof. Leroy Cronin Assembly of a Gigantic Polyoxometalate Cluster {W200Co8O660} in a Networked Reactor System Angewandte Chemie International Edition 51

Version of Record online: 23 NOV 2012 | DOI: 10.1002/anie.201206572

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A giant leap: A networked reactor system was used for the first time for the discovery and synthesis of new polyoxometalates, including the gigantic title system (see picture; Co red, W blue). The system comprises of three reactors connected in a triangular array with a central triply connected reactor. This system was used to screen multiple one-pot reactions and reaction variables for the automated syntheses of polyoxometalates.

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