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Shuang-Yan Lin, Dr. Wolfgang Wernsdorfer, Dr. Liviu Ungur, Prof. Annie K. Powell, Yun-Nan Guo, Prof. Dr. Jinkui Tang, Dr. Lang Zhao, Prof. Liviu F. Chibotaru and Prof. Hong-Jie Zhang Coupling Dy3 Triangles to Maximize the Toroidal Moment Angewandte Chemie International Edition 51

Article first published online: 9 NOV 2012 | DOI: 10.1002/anie.201206602

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A hexanuclear dysprosium(III) compound constructed by two Dy3 triangles in an edge-to-edge arrangement perfectly retains a nonmagnetic ground state and single-molecular-magnet behavior. Such an arrangement and the strong couplings over a μ4-O2− ion stabilize a similar arrangement of toroidal moments in the ground state, thus maximizing the toroidal moment of the complex. (Picture: Dy purple, C gray, N blue, O red.)

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